Table 2. Results of the Terpolymerization with Different Cocatalysts
Run No.a | Cocatalyst | Monomer (mol/L) | Yield (g) | Catalytic activityc | Mwd (×10-3) | Mnd (×10-3) | MWDd | Composition (%)e |
Ethylene | 1-hexene | DVBb | Ethylene | 1-hexene | DVBb |
5 | B1 | 0.4 | 0.8 | 0.2 | 6.05 | 7260 | 147 | 44 | 3.3 | 84.0 | 15.7 | 0.3 |
6 | B2 | 0.4 | 0.8 | 0.2 | 7.14 | 8568 | 139 | 51 | 3.2 | 83.3 | 16.3 | 0.4 |
Polymerization conditions: catalyst = 2.5µmol, B/Zr = 2.0, Al/Zr = 500, 50°C, 500 rpm, and 20 min.
Divinylbenzene.
Kg of polymer/(mol of catalyst·h).
Determined by gel permeation chromatography.
Determined by gel 1H NMR.